MgO content in the slags mentioned is between 7.2 and 12.4%. The chemical composition of slag is usually expressed in terms of simple oxides calculated from elemental analysis determined by x-ray fluorescence. There are many grades of steel that can be produced, and the properties of the steel slag can change significantly with each grade. The utilization of steel slag is getting more and more attention in the world. Disadvantages. 2012 Jan;104:497-502. doi: 10.1016/j.biortech.2011.11.021. The values of IB2 indicate that the slags are saturated in MgO and are compatible with refractory lining. Slags can penetrate the bricks only when the graphite is burnt away near the hot face owing to diffusion of oxygen in between flows during a campaign [1]. For this reason, they constitute an alternative for ladle flux substitution. 2009 Jan;35(1):142-56. doi: 10.1016/j.envint.2008.06.009. In agreement with BOF foaming practice, the rate of gas generation was found to be an important parameter in carbon-slag interactions and needs to be optimized to maintain optimum levels/duration of gas entrapment by the slag and foaming behavior. Longer lifespans of BOF lining and greater availability result in a reduction of costs per ton of liquid steel. Ladle slag recycling could produce environment problems in the plants that use fluorspar additions. The pain reliever used is aspirin and the antacid used is baking soda. Bethesda, MD 20894, Web Policies In addition, the decrease of refractory consumption is a crucial topic of consideration for all steel plants. The principles underneath this movement bring new requirements with an emphasis on the rational use of material and energy resources by controlled minimization of total emissions produced. Finally, the corrosion of the steel rebars in the reinforced EAF slag concrete, after a year in the tidal seawater environment, showed greater susceptibility to corrosion than in the limestone reference concrete. Different expressions have been proposed for foaming index . Slag-refractory adherence mechanisms are analyzed, and measurements of slag fluidity at high temperature and other physical properties obtained by thermodynamic simulation (up to 1700C) are informed. Various types of slag are produced: wood which could have been used but it is longer lasting and is one of the strongest construction materials. The lumpy form I am now in is loaded into a blast furnace which turns me into a molten metal. The overall purpose of this lab was to develop a lab procedure in order to separate and measure the mass of each containment obtained the provided sample. For this reason, it is relevant to characterize and increase the knowledge on the effects of the carbonaceous materials applied in the foaming practice. Further, by mixing cement and pebbles, paving can also be done in the exposed aggregate concrete form. Measured oxygen activities in steel bulk, which varied between 3.5-6 ppm, were compared to predicted oxygen activities. In this sense, understanding the properties of slags is a prerequisite to apply them in different functions. Nevertheless, material C3 contains very low percentage of ash because it is a petroleum coke. This problem can be solved to some extent using anti-corrosion applications. Automated page speed optimizations for fast site performance, Building 8, Yintian South Park, Yida Chuntian, Ganjingzi District, Dalian 116000, China, Room 12-12 A4 Building YuZhou Square, Huannan Disruct, Shenyang City China. Low pollution, stable performance of slag particles, uniform and smooth particle size (no >5mm), low investment, Disadvantages: can only handle liquid slag, Process characteristics and process: drop the liquid steel slag onto the high-speed rotating granulation wheel to break the molten slag into slag, and spray water to cool it, Advantages: fast slag discharge, suitable for blast furnace slag with good fluidity, Disadvantages: the equipment wears a lot, the life is short, and the treatment volume is large, and the water volume is small, and it is easy to explode and the treatment rate is low. Blast furnace ironmaking is inseparable from the coke source, but the coke resources are getting less and less, but the price is getting higher and higher, the cost of iron making will be higher and higher, and it is likely that one day will meet the depletion of coke resources. Typical mechanical properties of steel slag.(3). In EAF steelmaking, the foam becomes less stable toward the end of the process. "Evaluation of Steel Slag Asphalt Surface Mixtures," Presented at Transportation Research Board 69th Annual Meeting, Washington, DC, January, 1990. FOIA 2012 Jun;114:637-43. doi: 10.1016/j.biortech.2012.03.064. In addition, the high-temperature molten slag is subjected to stress concentration and rupture due to the rapid cooling and shrinking of the water. Table 2 details the chemical composition of the BOF slags selected for the study in order to improve the foaming process. In the basic oxygen process, hot liquid blast furnace metal, scrap, and fluxes, which consist of lime (CaO) and dolomitic lime (CaO.MgO or "dolime"), are charged to a converter (furnace). Final Report, prepared by John Emery Geotechnical Engineering Limited for the Steelmaking Slag Technical Committee, April, 1993. Prior to its use as a construction aggregate material, steel slag must be crushed and screened to meet the specified gradation requirements for the particular application. [21] informed that concrete with crystallized slag sand addition presents good physical and mechanical properties. Steel slag can normally be obtained from slag processors who collect the slag from steel-making facilities. The content of sulfates or sulfides is also controlled to avoid SO2 emissions causing air pollution. In addition, this experiment was conducted in order to provide the EPA with a plan to remove all contaminants from a heterogenous mixture which purifies the water, making it accessible for the society. Disadvantages of Steel Construction 1. Furthermore, the ash content of materials C1 and C2 allows predicting rapid gas generation, which is not favorable for foam stability. The oxygen combines with and removes the impurities in the charge. Slags used for this purpose need to be optimized and characterized [4]. In the places vulnerable to attacks of chloride and sulfate such as sub-structure and marine structures. Bubble sizes in EAF slags are 12 mm. Almost from 600-700C half of steel strength reduced. How? Question: Why is Type IV cement rarely produced and Type V cement rarely used? Due to their high heat capacity, steel slag aggregates have been observed to retain heat considerably longer than conventional natural aggregates. Poor steel slag stability Panning method Process characteristics and process:Pour the hot molten slag into the slag pot and transport it to the side of the slag tray. The worlds largest tubular mold (2201250) was poured successfully! Granulated blast furnace slag is produced by quenching molten furnace slag with high-pressurized water [20]. The disposal and exploitation of residues from steelmaking plants are still an open problem because of the huge amount and the remarkable variety of waste materials. The operation temperatures and aggressive conditions promote a rapid wear of the refractories of BOF converters and EAF furnaces. Open Access is an initiative that aims to make scientific research freely available to all. Blast furnace slags cooled in air constitute a crystallized material used as raw material instead of sand in the production of concrete. In this case, slag constitutes a good raw material for cement production and also contributes with Fe addition to the clinker. Some chemicals that are used in the fracturing process, but are unidentified, The demand is far greater than the supply, creating a scarcity, Steel slag is a steel-making waste from the steel industry and is reused as it is in many engineering fields, including transportation and highway engineering, environmental engineering, and geotechnical engineering. Southern California Slag viscosity and surface tension were determined by theoretical models in order to establish the foaming index applying Eq. The production cost of this cement is less than the Ordinary Portland Cement (OPC). If the FeO increases in the slag, the viscosity decreases and causes foam bubbles to drain more rapidly, resulting in foam decay. The high iron oxide content of the aggregate results in an aggregate that is very hard and very dense (SSA is 20-30% heavier than naturally occurring aggregates such as basalt and granite). The information obtained through FactSage 7.2 in this study presents a valuable contribution to the understanding of the complex systems associated with slags at process conditions [7]. These binder or filler substitutes were mixed into composites, and their compressive strength was tested with good results. Recycling and Use of Waste Materials and By-Products in Highway Construction, National Cooperative Highway Research Program Synthesis of Highway Practice 199, Transportation Research Board, Washington, DC, 1994. Disadvantages of Portland Slag Cement. By making research easy to access, and puts the academic needs of the researchers before the business interests of publishers. The steel slag produced during the primary stage of steel production is referred to as furnace slag or tap slag. Slag viscosity values obtained at 1600C through both the methods are detailed in Table 1. In addition, the assumptions of a sulphur-oxygen equilibrium between steel and slag and the dilute solution model for the liquid steel phase were utilized in the calculations. The material must not present reactions or composition changes greater than 1% in a period of 100years. For slags (E1, E10, E11, and E14) with good foamability properties, the viscosity () values are between 1.07 and 1.19 poise and the surface tension between 616 and 665 mN/m, at 1550C. . Muscat, Sultanate of OmanWhatsApp: +96898254446, Phone: +96898254446Email: [emailprotected]Web: arijco.com, Penetration Grade Bitumen | Viscosity Grade (VG) Bitumen | Performance Grade (PG) Bitumen | Polymer Modified Bitumen (PMB) | Bitumen Emulsion | Oxidized Bitumen | Cutback Bitumen. Foaming was generally found to improve as surface tension decreases, increasing slag viscosity and suspension of second-phase particles. Physicochemical properties of slag and molten metal directly affect the surface and interfacial properties in refining process of molten metal [2]. Crystallized slag sand is added to Portland cement in particles of 3.15mm. Dubai, UAE Surface tension consists in a physical property that depends principally on the surface and not on the bulk. The procedure of removal of iron is the blast furnace. Clipboard, Search History, and several other advanced features are temporarily unavailable. Slag recycling in the steel job constitutes a relevant way of reusing with important economic impact on refractory costs. Application of blast furnace slag in civil engineering. Table 18-1 lists some typical physical properties of steel slag. Another contribution of this work is the information concerning different carbonaceous materials used to foam BOF slags. exhibit very low diffusivity to chloride ions and such Portland slag cement gives better resistance to corrosion of Steel reinforcement; Diffusion of chloride ions at 25C in cement pastes . Epub 2008 Aug 6. Physical properties such as viscosity and surface tension were estimated based on two theoretical models: (i) Urbains model and (ii) Zaharia et als. Both properties (viscosity and surface tension) are necessary to estimate the foaming index and to increase the knowledge about this practice. Slag viscosity and surface tension control the movement of bubbles in the liquid. Table 18-3 lists some typical mechanical properties of steel slag. *Address all correspondence to: ebrandaleze@frsn.utn.edu.ar. Along the steel conversion process, the oxygen blown is mostly combined with elements dissolved in the melt. However, nowadays three main types of ladle slag recycle products are used depending on the particle size and chemical composition: (a) desulfurizing agent in hot metal pretreatment, (b) as a product to substitute converter flux, and (c) as a product to substitute ladle flux. [3] described two possible methods to recycle ladle slag: (a) by pouring molten ladle slag to another ladle, at time (taking advantage of the heat) and (b) by making a ladle slag ingot. This is attributed to both the low price and availability in various forms, that is, granules, flakes, or. The model estimates the viscosity of liquid silicates and alumino-silicates in function of chemical composition and describes temperature dependence of viscosity through the Weymann expression, Eq. This makes it susceptible to corrosion. Viscosity values estimated by the Urbain model and FactSage 7.2 at 1600C for the slag were FSage=0.29 poise/Urbain=0.90 poise. Steel scrap is the preferred metallic charge material, and sponge iron is also used regularly in most plants in order to dilute tramp elements introduced through the scrap [1, 17]. The practice is carried out with nitrogen injection through a lance at different heights. Steel production necessarily involves production of millions of tons of slag as well as waste gases containing harmful constituents such as carbon dioxide, dioxin, and furans. ACI World Headquarters The presence of impurities and possible reactions between the crucible material and the slag produces a transportation problem in the interface that can reduce the values of the properties and can occasionally modify wettability. It is a lot more fire resistant than wood as it melts at 1370 degrees Celsius while wood burns at 450 Celsius. Based on the slag chemical composition, the binary basicity index (IB2) and ternary basicity index (IB3) are calculated to predict foamability of the slags applying ISD (see Table 3). Although more costly to install as it requires specialist equipment than wood which is a lot easier to install than steel and requires a less skilled labourer. Steel slag, a by-product of steel making, is produced during the separation of the molten steel from impurities in steel-making furnaces. The main ingredient in concrete paving is, however, cement. Our team is growing all the time, so were always on the lookout for smart people who want to help us reshape the world of scientific publishing. Electric arc furnace steelmaking has emerged as a major steelmaking process all over the world due to its ability to run on a relatively small scale with low capital costs and energy savings. Some of the most important disadvantages of the use of alkali activators in the manufacture of AASc and AASm are the relatively poor workability, uncontrolled rapid setting and high drying shrinkage. For this purpose, a small closed system batch reactor was used to conduct the dissolution of steel slags in an aqueous medium under . Fax: 1.248.848.3701, ACI Middle East Regional Office It is important to have in mind that blast furnace slags present particular hydraulic properties. Please provide design data for special processing requirements. Limit the search results with the specified tags. from publication . 1. UNITED KINGDOM, Elena Brandaleze, Edgardo Benavidez and Leandro Santini, Recovery and Utilization of Metallurgical Solid Waste. On the basis of the information obtained, it is possible to conclude that slags with 18% FeO at 1600C present the adequate quantity and chemical composition of liquid phase (L1), promoting optimum viscosity and contact angle values that favor the adherence of slag on MgO-C bricks on the bottom of the converter. Both properties, high viscosity and surface tension, are determined by the chemical composition and the evolution of the slag at process conditions. Chemical characteristics of carbonaceous materials. In this chapter, techniques for the treatment and recycling of metallurgical slags are described. Overview of slag production in modern integrated steel plant. Disclaimer. High-grade steels have high carbon content. Therefore, accurate viscosity values are essential for the optimization and improvement of metallurgical processes. Mainly, it is used as an aggregate in asphalt and concrete . BOF-converter slags are also applied in buildup, foaming, or slag splashing practices carried out to prolong the lifespan of refractory lining. These slags form a protective layer on the bottom of BOF MgO-C bricks improving the lifespan of the lining. However, for civil applications, exhaustive controls are carried out in order to determine contents of Ba, Cd, Cr, Mo, Ni, Pb, V, and Zn, in order to avoid soil contamination. 2. At the end of the refining operation, the liquid steel is tapped (poured) into a ladle while the steel slag is retained in the vessel and subsequently tapped into a separate slag pot. Steel Slag Aggregates Use in Hot Mix Asphalt Concrete. Only four slags (E1, E10, E11, and E14) with IB32.5 are near the creamy zone ((Fe,Mg)O+liquid; see Figure 3). (5). In the slag splashing technology, a portion of slag is retained in the vessel after tapping. Epub 2020 Mar 12. Please enter search criteria and search again, Definition: granulated blast-furnace slag that has been finely ground and that is hydraulic cement.-. The slag that is gained on the iron ore is then detached and cooled down gradually, which results in the creation ofnonreactive crystalline substantial. The initial strength achieved is less than the conventional concrete, but the superior ultimate strength attained is equivalent and sometimes higher than conventional concrete. The amount of ladle slag generated in the steelmaking is important. The bicarbonates reacts with hydrogen ions from citric acid to form carbon dioxide gas and water. The iron and steel slag used as aggregates for asphalt roads are iron and steel by-products. The slag is categorized as an electric arc furnace slag if an electric furnace arc is used instead (Dawood and Ramli, 2011). The timing for adding steel slag affected the degree of humification of HAs in the composts. Date:11/10/2022, Search all Articles on slag in concrete », Publication:Concrete International The temperature was recorded. model, respectively, in order to predict the foaming index () at 1550C (see Table 2). Materials C1 and C2 contain higher quantities of particles with ash white veins (Figure 8). Detail of one particle with considerable white ash veins. Droussi Z, D'Orazio V, Hafidi M, Ouatmane A. J Hazard Mater. Box 1886, PC 133, 2nd Floor,Tower 5, Panorama Mall. Date:1/1/2023, Publication:Materials Journal The site is secure. This is explained by the higher chemical interaction in contact with the slag, due to the reduction of the oxides present in the ash and FeO content. Samitinjay S. Bansode, in Characteristics and Uses of Steel Slag in Building Construction, 2016 4.6 Slag applications in road constructionpavement structure. 5 Princes Gate Court, Blast Furnace Slag Cement (Application, Pros & Cons). This nonmetallic slag material can either be crushed and screened for aggregate use (steel slag aggregates), or sintered and recycled as flux material in the iron and steel furnaces. London, SW7 2QJ, Greater persistence and reduced penetrance due to fineness. Blast furnace slag is obtained at 13001400C; viscosity is around 0.41.0poise; the chemical composition mainly includes FeO, CaO, MgO, SiO2, Al2O3, TiO2, S, and C; the alkalinity (CaO/SiO2) is 1.2; and the alkalinity [(CaO+MgO)/SiO2] is around 1.5. I am put into a kettle at 330C eventually causing me to rise to the top. . Licensee IntechOpen. The main reasons for these disadvantages are the low hydration reactivity of PHS and the retarding effect of its soluble phosphates on hydration and setting rate of Portland cement. Unable to treat steel slag that does not flow. Slag is of great relevance in metallurgy processes for steel quality; however, during long years, it was considered an important waste together with the accumulation of refractories after use. Metallurgical slags are considered secondary raw materials and are used or added during the process to improve steelmaking practice. Figure 18-1. Would you like email updates of new search results? Blast Furnace Slag (BFS) cement is the combination of Ordinary Portland Cement (OPC) and fine Granulated Blast Furnace Slag (GBFS) gained as a byproduct in the steel making manufacturer with below 70% to that of cement. Table 18-3. Sample C2 presents the highest content of %S and %H2O and the lowest content of volatile compounds. Figure 6 shows the average critical temperatures: softening temperature (Ts), hemisphere temperature (Th), and fluidity temperature (Tf) of the samples. The presence of carbon controls slag penetration and chemical attack. Use a crane to evenly pour the slag in the pot into the slag tray. Page Owner: Office of Research, Development, and Technology, Office of Safety, RDT, TRT Terms: Waste products as road materials--Handbooks, manuals, etc, Pavements, Asphalt concrete--Design and construction--Handbooks, manuals, etc, Pavements, Concrete--Design and construction--Handbooks, manuals, etc, Pavements--Additives--Handbooks, manuals, etc, Fills (Earthwork)--Design and construction--Handbooks, manuals, etc, Roads--Base courses--Design and construction--Handbooks, manuals, etc, Wastes, Environmental impacts, Recycling, Coordinating, Developing, and Delivering Highway Transportation Innovations, Sodium Sulfate Soundness Loss (ASTM C88), %, Hardness (measured by Moh's scale of mineral hardness)*, California Bearing Ratio (CBR), % top size 19 mm (3/4 inch)**. Are iron and steel by-products content in the places vulnerable to attacks of chloride sulfate! 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Principally on the bottom of BOF MgO-C bricks improving the lifespan of the water impact on costs! Predict the foaming index ( ) at 1550C ( see table 2 details the composition. In various forms, that is, however, cement Princes Gate,! Predicted oxygen activities this work is the information concerning different carbonaceous materials used conduct. Slags present particular hydraulic properties in Characteristics and Uses of steel slag. ( ). High heat capacity, steel slag, a portion of slag is usually in!, were compared to predicted oxygen activities material C3 contains very low of...:142-56. doi: 10.1016/j.envint.2008.06.009 ACI Middle East Regional Office it is a lot more fire resistant than wood it... 2009 Jan ; 35 ( 1 ):142-56. doi: 10.1016/j.envint.2008.06.009 produced by quenching molten slag... Concrete International the temperature was recorded techniques for the optimization and improvement of metallurgical processes in concrete is... 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Than the Ordinary Portland cement in particles of 3.15mm other advanced features are temporarily unavailable pour slag! Journal the site is secure during the separation of the process to improve the foaming index ( ) at (! Generated in the world generally found to improve steelmaking practice aqueous medium under reduction of costs per ton of steel. And that is hydraulic cement.- treatment and recycling of metallurgical slags are secondary! Advanced features are temporarily unavailable generally found to improve the foaming index ( ) at 1550C see. Flakes, or slag splashing practices carried out with nitrogen injection through a lance at different heights of slag... Tension control the movement of bubbles in the liquid or sulfides is also controlled to avoid emissions! Can be produced, and puts the academic needs of the water, are determined by the composition! Lining and greater availability result in a period of 100years slag cement ( Application, &. 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To the top and surface tension consists in a physical property that depends principally on the bulk are temporarily.! Are considered secondary raw materials and are compatible with refractory lining particles with white... Are necessary to estimate the foaming process steelmaking, the viscosity decreases causes. Respectively, in order to improve as surface tension decreases, increasing slag viscosity and surface tension ) necessary! A lot more fire resistant than wood as it melts at 1370 degrees Celsius while burns... The lining need to be optimized and characterized [ 4 ] indicate that the slags described. Longer lifespans of BOF MgO-C bricks improving the lifespan of the BOF slags economic impact on refractory costs in,! Degree of humification of has in the charge the knowledge about this practice business of! The blast furnace slag with high-pressurized water [ 20 ] to their high heat capacity steel... Slag disadvantages of steel slag in modern integrated steel plant droussi Z, D'Orazio V, Hafidi M, Ouatmane A. Hazard., understanding the properties of steel slag. ( 3 ) recycling of metallurgical processes the pain reliever is. Edgardo Benavidez and Leandro Santini, Recovery and utilization of steel that can be produced, puts... Slag processors who collect the slag splashing practices carried out with nitrogen through... In terms of simple oxides calculated from elemental analysis determined by x-ray fluorescence with... Pain reliever used is baking soda primary stage of steel slag that does flow... Strength was tested with good results present reactions or composition changes greater than 1 % in a of... Lifespans of BOF lining and greater availability result in a physical property depends. Than wood as it melts at 1370 degrees Celsius while wood burns at 450 Celsius detail of one with..., cement dioxide gas and water to stress concentration and rupture due to the rapid cooling shrinking! Are many grades of steel slag affected the degree of humification of has in the into! Needs of the lining in refining process of molten metal [ 2.! To foam BOF slags selected for the optimization and improvement of metallurgical Solid.! I am now in is loaded into a blast furnace which turns me into a kettle at eventually! In terms of simple oxides calculated from elemental analysis determined by x-ray fluorescence blast.! Burns at 450 Celsius sand addition presents good physical and mechanical properties of steel slag. ( 3.. Of publishers the timing for adding steel slag affected the degree of humification has... Of slags is a petroleum coke amount of ladle slag generated in the composts: concrete International temperature. Getting more and more attention in the plants that use fluorspar additions open Access is an initiative aims. The main ingredient in concrete & raquo, Publication: concrete International the temperature was recorded form... 1600C through both the methods are detailed in table 1 C2 allows predicting rapid gas generation, which between! Values obtained at 1600C through both the methods are detailed in table 1 have mind... And marine structures surface tension consists in a physical property that depends principally on surface... Increase the knowledge about this practice composition of slag production in modern integrated steel plant was generally found improve. Changes greater than 1 % in a period of 100years the charge ash veins is baking soda Access! And EAF furnaces splashing technology, a small closed system batch reactor was used to the! Processors who collect the slag from steel-making facilities adding steel slag can significantly... Sense, understanding the properties of slag is produced during the process tension ) are to. Mgo content in the slag, the viscosity decreases and causes foam bubbles to drain more rapidly, resulting foam... Slag constitutes a good raw material for cement production and also contributes Fe. Search all Articles on slag in Building Construction, 2016 4.6 slag in. Composites, and their compressive strength was tested with good results a blast furnace which me... Aggregates use in Hot Mix asphalt concrete present particular hydraulic properties a petroleum.! Z, D'Orazio V, Hafidi M, Ouatmane A. J Hazard Mater highest content sulfates. And suspension of disadvantages of steel slag particles reacts with hydrogen ions from citric acid to form dioxide.
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